Product ID:(ETHYLENEDINITRILO) TETRAACETIC ACID (SUPP
MSDS Date:06/24/1992
FSC:6810
NIIN:00N039742
MSDS Number: BRJXP

FISHER SCIENTIFIC

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

LESIONS AND TUBULAR NECROSIS, INTERNAL HEMORR,

RTECS: 9999999ZZ

ADMINISTRATION MAY LEAD TO ELECTROLYTE IMBALANCE AND

RTECS: 9999999ZZ

NIOSH/MSHA APPRVD AIR-PURIFYING RESP W/HEPA

RTECS: 9999999ZZ

HEPA FILTER. ANY NIOSH/MSHA APPRVD TYPE 'C'

RTECS: 9999999ZZ

CONTINUOUS-FLOW MODE. ANY NIOSH/MSHA APPRVD SCBA.

RTECS: 9999999ZZ

APPRVD SCBA THAT HAS FULL FACEPIECE & IS OPER IN

RTECS: 9999999ZZ

APPRVD SUPP-AIR RESP THAT HAS FULL FACEPIECE AND IS

RTECS: 9999999ZZ

COMBINATION WITH AUXILIARY SCBA OPERATED IN

RTECS: 9999999ZZ

(ETHYLENEDINITRILO) TETRAACETIC ACID TETRASODIUM SALT

CAS: 64-02-8

RTECS: AH5075000

Fraction By Weight: 100%

UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM

RTECS: 9999999ZZ

TREAT SYMP & SUPPORTIVELY. GET MED ATTN IMMED. IF

RTECS: 9999999ZZ

NO SPECIFIC ANTIDOTE. TREAT

RTECS: 9999999ZZ

SALTS MAY CHELATE LEAD, MAGNESIUM, ZINC, &

RTECS: 9999999ZZ

CAUSING THEIR INCR ABSORP & THEREBY INCR TOTAL BODY

RTECS: 9999999ZZ

PRLNGD CONT W/SKIN MAY CAUSE MOD IRRIT & POSS MILD

RTECS: 9999999ZZ

PARENTERAL ADMIN

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: INHAL OF DUSTS/MISTS OF
EDTA SALTS MAY CAUSE MUC MEMB IRRIT W/SORE THROAT & COUGHING. SKIN:
CONT MAY CAUSE IRRIT W/REDNESS & PAIN. APPLIC OF 500 MG TO RABBIT
SKIN FOR 24 HRS RSLTD IN MOD IRRIT. EYE: CONT MAY CAUSE IRRIT
W/REDNESS & PAIN. MAY CAUSE TRANSIENT CORNEAL INJ. SOLNS OF EDTA
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: TETRASODIUM SALT ARE SUFF ALKALINE TO
BE INJURIOUS TO EYE.APPLIC OF 1900 UG TO RABBIT EYES CAUSED
IRRIT.APPLIC OF 100 MG TO RABBIT EYES FOR 24 HRS CAUSED MOD IRRIT.
INGEST: SOLNS OF SALTS OF EDTA ARE EXTREMELY IRRIT TO GI SYS.
ALTHOUGH POORLY ABSORB,IF SUFF AMTS ARE INGEST SYS TOX MAY RSLT.
EDTA & ITS(ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE FROM EXPOS AREA TO FRESH AIR IMMED.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. TREAT SYMP
& SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG &
SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS
OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MINS). GET
MED ATTN IMMED. EYE: WASH IMMED W/LRG AMTS OF WATER/NORM SALINE
(SUPDAT)

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM.
FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . AVOID BREATHING HAZARDOUS VAPORS, KEEP
UPWIND.
Unusual Fire/Explosion Hazard:UNKNOWN FIRE AND EXPLOSION HAZARD.

Spill Release Procedures:NO SPECIAL PRECAUTIONS INDICATED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM
LEVS FOUND IN WORK PLACE, MUST BE BASED ON SPECIFIC OPER, MUST NOT
EXCEED WORKING LIMITS OF RESP & MUST BE JOINTLY APPRVD BY
NIOSH/MSHA. ANY NIOSH/MSHA A PPRVD DUST & MIST RESP. ANY (ING 11)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION. VENTILATION EQUIPMENT
MUST BE EXPLOSION PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS)
CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN CONT W/SUBSTANCE. WHERE
THERE(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TRADE NAME/PART #: TETRASODIUM SALT, S-657. PH: 11.3-11.8 @ 1% SOLN.
MATLS TO AVOID: FIRE & EXPLO HAZ. OTHER PROT EQUIP: IS ANY POSS
THAT EMPLOYEE'S EYES MAY BE EXPOS TO SUBSTANCE, EMPLOYER SHOULD PRO
VIDE AN EYE WASH FOUNTAIN W/IN IMMED WORK AREA FOR EMER USE. FIRST
AID PROC: FOR AT LST 15 MINS, OCCAS LIFTING (ING 2)

Melt/Freeze Pt:M.P/F.P Text:>572F,>300C
pH:SUPDAT
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER.

Stability Indicator/Materials to Avoid:YES
ACIDS: INCOMPAT. ALUMINUM: MAY FORM FLAMM HYDROGEN GAS. METALS: MAY
FORM FLAMM HYDROGEN GAS.OXIDIZERS (STRONG): (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND HAZARDOUS OXIDES OF CARBON, NITROGEN, AND SODIUM.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .

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